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However, it is not a biunivocal correspondence, for instance the classical counterexample is the Motzkin Polynomial:
$$M(x,y) = x^4y^2+x^2y^4 + 1 - 3x^2y^2.$$
The General problem of polynomial nonnegativity is NP-hard. Yet, sum-of-squares decomposition is a reasonably close approximation to the nonnegative characterization. Also, the bijection holds, easily follows from Cholesky decompositon:
$$\text{Let } m = (1 , x_1, x_2, ..., x_1^d, x_1^{d-1} x_2, ..., x_n^d) \text{ where } d \text{ is the polynomial degree}.$$
$$\text{Let } N = \binom{n+d}{d} $$
$$\sum_{i=1}^k q_i^2(x)_{j=1}^n = p(x)_{j=1}^n \Leftrightarrow \exists G \in \mathbb{R}^{N \times N} : G = G^t \land G \succeq 0 \land p(x)_{j=1}^n = m^t G m .$$
The constraints imposed by $p(x)_{j=1}^n = m^t G m$ generates linear constraints, plus the $G \succeq 0$ implies a semidefinite feasibility problem.
About
Studies in sum-of-squares and real algebra for satisfability in polynomials, obtained via semidefinite programming; as well as studies in exatification.