diff --git a/prdoc/pr_12679.prdoc b/prdoc/pr_12679.prdoc
new file mode 100644
index 000000000000..6ae099b9e746
--- /dev/null
+++ b/prdoc/pr_12679.prdoc
@@ -0,0 +1,20 @@
+title: '[pallet-revive] reject r/s out of range in the ecRecover precompile'
+
+doc:
+- audience: Runtime Dev
+  description: |
+    The `0x01` ecRecover precompile only validated `v`, leaving `r` and `s`
+    unchecked. Depending on the `sp_io` backend, an out of range `s` can be
+    reduced modulo the curve order `N` instead of being rejected, so a
+    signature that go-ethereum rejects could recover an address here. That is a
+    consensus divergence, and it lets an attacker mint a second valid signature
+    by adding `N`, defeating malleability and replay assumptions in contracts.
+
+    The precompile now rejects `r` or `s` equal to zero or greater than or equal
+    to `N` before recovery, returning the empty output (Solidity `address(0)`).
+    This matches go-ethereum `ValidateSignatureValues` with `homestead=false`, so
+    high `s` values in the range `1..N` are still accepted.
+
+crates:
+- name: pallet-revive
+  bump: patch
diff --git a/substrate/frame/revive/src/precompiles/builtin/ecrecover.rs b/substrate/frame/revive/src/precompiles/builtin/ecrecover.rs
index 25cae2fce202..a502a03d26d0 100644
--- a/substrate/frame/revive/src/precompiles/builtin/ecrecover.rs
+++ b/substrate/frame/revive/src/precompiles/builtin/ecrecover.rs
@@ -22,6 +22,13 @@ use crate::{
 };
 use alloc::vec::Vec;
 use core::{marker::PhantomData, num::NonZero};
+use sp_core::U256;
+
+/// Order of the secp256k1 curve; valid `r` and `s` lie in `1..N`.
+const SECP256K1_N: [u8; 32] = [
+	0xff, 0xff, 0xff, 0xff, 0xff, 0xff, 0xff, 0xff, 0xff, 0xff, 0xff, 0xff, 0xff, 0xff, 0xff, 0xfe,
+	0xba, 0xae, 0xdc, 0xe6, 0xaf, 0x48, 0xa0, 0x3b, 0xbf, 0xd2, 0x5e, 0x8c, 0xd0, 0x36, 0x41, 0x41,
+];
 
 pub struct EcRecover<T>(PhantomData<T>);
 
@@ -54,6 +61,15 @@ impl<T: Config> PrimitivePrecompile for EcRecover<T> {
 			return Ok(Vec::new());
 		}
 
+		// Reject r,s outside 1..N to match go-ethereum (homestead=false); some sp_io backends
+		// reduce out-of-range s modulo N, diverging and allowing malleability.
+		let n = U256::from_big_endian(&SECP256K1_N);
+		let r = U256::from_big_endian(&sig[0..32]);
+		let s = U256::from_big_endian(&sig[32..64]);
+		if r.is_zero() || r >= n || s.is_zero() || s >= n {
+			return Ok(Vec::new());
+		}
+
 		let data = match sp_io::crypto::secp256k1_ecdsa_recover(&sig, &msg) {
 			Ok(pubkey) => {
 				let mut address = sp_io::hashing::keccak_256(&pubkey);
diff --git a/substrate/frame/revive/src/precompiles/builtin/testdata/1-ecRecover.json b/substrate/frame/revive/src/precompiles/builtin/testdata/1-ecRecover.json
index b033cbbb8247..3e29cdb969d2 100644
--- a/substrate/frame/revive/src/precompiles/builtin/testdata/1-ecRecover.json
+++ b/substrate/frame/revive/src/precompiles/builtin/testdata/1-ecRecover.json
@@ -33,5 +33,40 @@
     "Gas": 3000,
     "Name": "InvalidHighV-bits-3",
     "NoBenchmark": false
+  },
+  {
+    "Input": "18c547e4f7b0f325ad1e56f57e26c745b09a3e503d86e00e5255ff7f715d3d1c000000000000000000000000000000000000000000000000000000000000001c73b1693892219d736caba55bdb67216e485557ea6b6af75f37096c9aa6a5a75ffffffffffffffffffffffffffffffffebaaedce6af48a03bbfd25e8cd0364141",
+    "Expected": "",
+    "Gas": 3000,
+    "Name": "SValueEqualToN",
+    "NoBenchmark": false
+  },
+  {
+    "Input": "18c547e4f7b0f325ad1e56f57e26c745b09a3e503d86e00e5255ff7f715d3d1c000000000000000000000000000000000000000000000000000000000000001c73b1693892219d736caba55bdb67216e485557ea6b6af75f37096c9aa6a5a75ffffffffffffffffffffffffffffffffebaaedce6af48a03bbfd25e8cd0364142",
+    "Expected": "",
+    "Gas": 3000,
+    "Name": "SValueGreaterThanN",
+    "NoBenchmark": false
+  },
+  {
+    "Input": "18c547e4f7b0f325ad1e56f57e26c745b09a3e503d86e00e5255ff7f715d3d1c000000000000000000000000000000000000000000000000000000000000001c73b1693892219d736caba55bdb67216e485557ea6b6af75f37096c9aa6a5a75f0000000000000000000000000000000000000000000000000000000000000000",
+    "Expected": "",
+    "Gas": 3000,
+    "Name": "SValueZero",
+    "NoBenchmark": false
+  },
+  {
+    "Input": "18c547e4f7b0f325ad1e56f57e26c745b09a3e503d86e00e5255ff7f715d3d1c000000000000000000000000000000000000000000000000000000000000001cfffffffffffffffffffffffffffffffebaaedce6af48a03bbfd25e8cd0364141eeb940b1d03b21e36b0e47e79769f095fe2ab855bd91e3a38756b7d75a9c4549",
+    "Expected": "",
+    "Gas": 3000,
+    "Name": "RValueEqualToN",
+    "NoBenchmark": false
+  },
+  {
+    "Input": "18c547e4f7b0f325ad1e56f57e26c745b09a3e503d86e00e5255ff7f715d3d1c000000000000000000000000000000000000000000000000000000000000001c0000000000000000000000000000000000000000000000000000000000000000eeb940b1d03b21e36b0e47e79769f095fe2ab855bd91e3a38756b7d75a9c4549",
+    "Expected": "",
+    "Gas": 3000,
+    "Name": "RValueZero",
+    "NoBenchmark": false
   }
 ]